Please use this identifier to cite or link to this item:
http://hdl.handle.net/20.500.11889/7651
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Abuhijleh, A. Latif | - |
dc.date.accessioned | 2023-02-09T07:48:50Z | - |
dc.date.available | 2023-02-09T07:48:50Z | - |
dc.date.issued | 2011 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11889/7651 | - |
dc.description.abstract | Mononuclear complex bis(aspirinato) bis(2-methylimidazole) copper(II), Cu(asp)2 (2-MeIm)2 (1), has been synthesized and spectroscopically characterized. The biomimetic catalytic activities of this complex and our previously characterized complexes, Cu(asp)2 (1,2-MeIm)2 (2), Cu(Hsal)2 (1,2-MeIm)2 (3), and Cu(sal)(2- MeIm)3, (4) [H2sal= salicylic acid and MeIm=methylimidazole], for the oxidation of 3,5-di-tert butylcatechol to the corresponding o-quinone and the oxidative dealkylation of 2,4,6-tri-tert-butylphenol to 2,6-di-tert-butyl-1,4-benzoquinone and 4,6-di-tert-butyl-1,2-benzoquinone as the main products are reported. Complexes 1 and 2 are found to be potent SOD mimics and their SOD activities are compared with those obtained previously for complexes 3 and 4. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Inorganic Chemistry Communications | en_US |
dc.subject | Mononuclear copper(II) aspirinate Catecholase Oxidative dealkylation of phenol | en_US |
dc.subject | Mononuclear copper(II) aspirinate | en_US |
dc.subject | Catecholase | en_US |
dc.subject | SOD mimics | en_US |
dc.title | Mononuclear copper(ll) aspirinate or salicylate complexes with methylimidazoles as biomimetic catalysts for oxidative dealkylation of a hindered phenol, oxidation of catechol and their superoxide scavenging activities | en_US |
dc.type | Article | en_US |
newfileds.department | Science | en_US |
newfileds.item-access-type | open_access | en_US |
newfileds.thesis-prog | none | en_US |
newfileds.general-subject | none | en_US |
dc.identifier.doi | 10.1016/j.inoche.2011.02.029 | - |
item.grantfulltext | open | - |
item.fulltext | With Fulltext | - |
item.languageiso639-1 | other | - |
Appears in Collections: | Fulltext Publications |
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MONONU~1.PDF | 357.27 kB | Adobe PDF | View/Open |
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