Please use this identifier to cite or link to this item:
Title: ChemInform abstract: studies of the reactions of Ferric Iron with Glutathione and some related Thiols. Part V > solid complexes containing Iron II and Glutathione Or Iron III
Authors: Hamed, Mazen
Silver, Jack
Morrison, Ian E. G.
Morrison, Ian E. G.
Issue Date: Nov-1985
Publisher: ResearchGate
Abstract: A number of polymeric iron(III) oxidised glutathione materials have been prepared. Mijssbauer spectroscopic, magnetic susceptibility data and electronic reflectance spectra studies on these iron- (III) materials are discussed. the red complex contained iron(II1). A scheme for the iron catalyzed oxidation of GSH . by molecular oxygen was presented. We have also reported a study of the reaction of GSH with protoporphyrin IX iron(II1); little evidence for reduction of the Fe(II1) in the porphyrin was found [4]. Two stoichiometries 1: 1 and 1:2 have been established for iron(glutathione materials. Spectroscopic studies show that the 1:l materials contain high spin iron(I1) in distorted five and six coordinated environments, whereas the 1:2 materials contain only distorted six-coordinated high spin iron(I1). The nature of the coordinating ligands are discussed.
Description: Jack,Silver:Brunel University London
Appears in Collections:Fulltext Publications

Files in This Item:
File Description SizeFormat
ChemInform Abstract STUDIES OF THE REACTIONS OF FERRIC IRON .pdf900.03 kBAdobe PDFView/Open
Show full item record

Page view(s)

Last Week
Last month
checked on Jun 27, 2024


checked on Jun 27, 2024

Google ScholarTM


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.