Please use this identifier to cite or link to this item:
http://hdl.handle.net/20.500.11889/4158
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Abu Hijleh, Abdullatif | - |
dc.contributor.author | Woods, Clifton | - |
dc.date.accessioned | 2017-01-19T09:57:42Z | - |
dc.date.available | 2017-01-19T09:57:42Z | - |
dc.date.issued | 1993-03-23 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11889/4158 | - |
dc.description | valproate is an anticonvulsant drug and are used for epilepsy patients | en_US |
dc.description.abstract | Four mononuclear imidazole adducts of copper(I1) valproate have been prepared and characterized with IR, UV-Vis, EPR spectroscopic techniques and fast atom bombardment mass spectrometry. The catecholase-mimetic-catalytic activities of the complexes have been determined by monitoring the formation of o-quinone from catechol. The catalytic activities of the mononuclear complexes are lower than that of the dinuclear copper(H) valproate.The complexes with 2-methylimidazole and 1,2-dimethylimidazole show slightly lower activities that the imidazole and N-methylimidazole complexes. The structure of Cu(Val)z(2mIm), (Val =valproate; 2mIm = 2-methylimidazole) has been determined. The complex crystallizes in the p2,/c space group with unit cell dimensions of a =9.309(l),b = 12.456(2), c = 12.560(2) A, p = 99.84(l)“, I/= 1435.0(3) b;‘, Z = 2. | en_US |
dc.description.sponsorship | Birzeit University and University of Tennessee | en_US |
dc.language.iso | en | en_US |
dc.publisher | Elsevier | en_US |
dc.subject | Copper compounds - Synthesis | en_US |
dc.subject | Copper compounds - Therapeutic use | en_US |
dc.subject | Copper crystals - Spectra | en_US |
dc.subject | Imidazoles | en_US |
dc.subject | Catechol | en_US |
dc.subject.lcsh | Copper crystals | - |
dc.title | Characterization and catecholase-mimetic behavior of imidazole adducts of copper(II) valproate. Crystal structure of the 2-methylimidazole adduct | en_US |
dc.type | Article | en_US |
newfileds.department | Science | en_US |
newfileds.corporate-author | Clifton Woods | en_US |
newfileds.item-access-type | open_access | en_US |
newfileds.thesis-prog | none | en_US |
newfileds.general-subject | Natural Sciences | العلوم الطبيعية | en_US |
item.languageiso639-1 | other | - |
item.fulltext | With Fulltext | - |
item.grantfulltext | open | - |
Appears in Collections: | Fulltext Publications |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
copper valp.-imidazoles.pdf | 658.2 kB | Adobe PDF | View/Open |
Page view(s)
140
Last Week
2
2
Last month
6
6
checked on Apr 14, 2024
Download(s)
43
checked on Apr 14, 2024
Google ScholarTM
Check
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.