Please use this identifier to cite or link to this item:
http://hdl.handle.net/20.500.11889/3972
DC Field | Value | Language |
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dc.contributor.author | Abu Hijleh, Abdullatif | - |
dc.date.accessioned | 2016-12-19T09:46:42Z | - |
dc.date.available | 2016-12-19T09:46:42Z | - |
dc.date.issued | 1996-04-29 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11889/3972 | - |
dc.description.abstract | A synthetic investigation of copper(II) ibuprofenate (lbup) addition compounds with 2,2'-bipyridine (bpy), 1,10-phenanthroline (phen) and 2,9-dimethyl-l,10-phenanthroline (dmph) has led to the isolation of dinuclear adducts of the forms [Cu(Ibup)2(bpy)]z'4H20 (1) and [Cu(Ibup)2(phen)]2 (2) and a mononuclear adduct Cu(lbup)2(dmph) (3). Spectroscopic data for adducts 1 and 2 are consistent with a dinuclear structure with two CuN202+O chromophors. Each copper is coordinated with two ibuprofenate bridges, a terminal diimine molecule and a monodentate ibuprofenate group complete five-coordination at each metal atom. Spectroscopic data for adduct 3 are consistent with a mononuclear structure having a very distorted square- pyramidal CuN202+O chromophore. The Cu H atom is coordinated to two nitrogen atoms from a chelating dmph ligand, two carboxylic oxygens of a bidentate ibuprofenate ion and an oxygen atom of a monodentate carboxylic group of a second ibuprofenate ion. The reduction of adduct (3) by ascorbic acid produced stable red copper(I) complex of the form [Cu(dmph)2] (Ibup) (4). Spectral data of this adduct indicated that the cation has distorted tetrahedral geometry about the copper atom. The effect of I and 2 on the rate of hydrolysis of bis(p-nitrophenyl) phosphate (BNPP) have been examined in aqueous methanol solution at 70'C and pH 7.4 | - |
dc.language.iso | en_US | en_US |
dc.subject.lcsh | Copper compounds - Synthesis | - |
dc.subject.lcsh | Copper compounds - Analysis | - |
dc.subject.lcsh | Ibuprofen | - |
dc.title | Synthesis and characterization of copper-ibuprofenate complexes with 2,2'-bipyridine and 1,10-phenanthrolines and their hydrolytic activities in phosphate diester cleavage | en_US |
dc.type | Article | en_US |
newfileds.department | Science | en_US |
newfileds.item-access-type | open_access | en_US |
newfileds.thesis-prog | none | en_US |
item.grantfulltext | open | - |
item.fulltext | With Fulltext | - |
item.languageiso639-1 | other | - |
Appears in Collections: | Fulltext Publications |
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copper ibuprofen-diimines.pdf | 641.42 kB | Adobe PDF | View/Open |
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