Please use this identifier to cite or link to this item:
http://hdl.handle.net/20.500.11889/3928
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Abu Hijleh, Abdullatif | |
dc.contributor.author | Abu Ali, Hijazi | |
dc.contributor.author | Abdul-Hamid, Emwas | |
dc.date.accessioned | 2016-12-13T11:21:37Z | |
dc.date.available | 2016-12-13T11:21:37Z | |
dc.date.issued | 2009 | |
dc.identifier.uri | http://hdl.handle.net/20.500.11889/3928 | |
dc.description.abstract | The dinuclear complex tetra(μ-valproato) dirhodium(II), Rh2(valp)4 (1), and its bis-adducts with theophylline, Rh2(valp)4(ThH)2 (4), or caffeine, Rh2(valp)4(Caf)2 (5), have been synthesized and characterized by elemental analysis, IR, UV-Vis, magnetic moment, 1H and 13C NMR spectroscopic techniques. Spectral data for the complexes are consistent with a dinuclear structure as found for rhodium (II) tetracarboxylate adducts. Theophylline and caffeine bases in complexes 4 and 5, respectively, are axially coordinated to rhodium (II) atoms through the sterically hindered N(9) site. This is confirmed by X-ray crystal structure analyses of complexes 4 and 5. | en_US |
dc.language.iso | en_US | en_US |
dc.subject | Rhodium compounds - Synthesis | en_US |
dc.subject | Rhodium compounds - Physiological effect | en_US |
dc.subject.lcsh | Anticonvulsants - Analysis | |
dc.subject.lcsh | Cancer - Chemotherapy | |
dc.subject.lcsh | Ligands (Biochemistry) | |
dc.title | Synthesis, spectral and structural characterization of dinuclear rhodium (II) complexes of the anticonvulsant drug valproate with theophylline and caffeine | en_US |
dc.type | Article | en_US |
newfileds.department | Science | en_US |
newfileds.item-access-type | open_access | en_US |
newfileds.thesis-prog | none | en_US |
newfileds.general-subject | Human Biology, Medicine and Health Sciences | الطب والعلوم الطبية | en_US |
item.languageiso639-1 | other | - |
item.fulltext | With Fulltext | - |
item.grantfulltext | open | - |
Appears in Collections: | Fulltext Publications |
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Synthesis, spectral and structural characterization of dinuclear rhodium (II) complexes of the anticonvulsant drug valproate with theophylline and caffeine.pdf | 551.32 kB | Adobe PDF | View/Open |
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