Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.11889/2650
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dc.contributor.authorLaila, Abdalhamid
dc.date.accessioned2016-10-15T08:53:24Z
dc.date.available2016-10-15T08:53:24Z
dc.date.issued2013
dc.identifier.urihttp://hdl.handle.net/20.500.11889/2650
dc.description.abstractThis paper describes the kinetics and mechanism of oxidation of several monohydric alcohols to the corresponding aldehydes and ketones by bis(quinuclidine)bromine(I) bromide in the presence of pyridinium trifluoroacetate. All evidence from the thermodynamic parameters, deuterium kinetic isotope effect, and Hammett reaction constants supports a two-step mechanism and suggests that the transfer of hydride ion from the substrate to the oxidant is the rate-determining step.
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.subject.lcshCarbonyl compounds
dc.subject.lcshStructure–reactivity relationship
dc.subject.lcshRate constants
dc.titleKinetics and mechanism of oxidation of alcoholsen_US
newfileds.item-access-typeopen_accessen_US
newfileds.general-subjectChemistry and Allied Sciencesen_US
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