Please use this identifier to cite or link to this item:
http://hdl.handle.net/20.500.11889/4224
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Abu Hijleh, Abdullatif | - |
dc.contributor.author | Woods, Clifton | - |
dc.date.accessioned | 2017-02-13T10:36:01Z | - |
dc.date.available | 2017-02-13T10:36:01Z | - |
dc.date.issued | 1992 | - |
dc.identifier.uri | http://hdl.handle.net/20.500.11889/4224 | - |
dc.description | Article in Journal of Chemical Society | en_US |
dc.description.abstract | The products of the reactions of 1,2-dimethyIimidazole and N-methylimidazole with tetrakis(ferr0-cenecarboxylato)dicopper( 11) have been isolated and characterized by single-crystal X-ray diffraction. They are the monomeric species cis- bis( 1,2-dimethylirnidazole) bis(ferrocenecarboxylato)copper( 11) 1 and trans- bis (ferrocenecarboxylato) bis(N- methylimidazo1e)copper ( I I) 2, respectively. In each complex the copper ion is in a square-planar environment consisting of two imidazole nitrogen atoms and a carboxylate oxygen atom from each ferrocenecarboxylate ligand. The second oxygen atoms of the carboxylate functionalities are involved in weak interactions with the copper ions. The q5-C5H, and q5-C5H5 rings of the ferrocenyl moieties are nearly eclipsed with deviations from the eclipsed conformation of 9.7 and 5.5" for 1 and 4.4" for 2. | en_US |
dc.language.iso | en_US | en_US |
dc.publisher | Royal Society of Chemistry | en_US |
dc.subject | Copper compounds - Synthesis | en_US |
dc.subject | Copper compounds - Analysis | en_US |
dc.title | Syntheses and molecular structures of cis and trans monomeric ferrocenecarboxylatocopper(l1) complexes with imidazole derivatives | en_US |
dc.type | Article | en_US |
newfileds.department | Science | en_US |
newfileds.item-access-type | open_access | en_US |
newfileds.thesis-prog | none | en_US |
newfileds.general-subject | none | en_US |
item.grantfulltext | open | - |
item.fulltext | With Fulltext | - |
item.languageiso639-1 | other | - |
Appears in Collections: | Fulltext Publications |
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Journal of the Chemical Society.pdf | 515.56 kB | Adobe PDF | View/Open |
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